Mesquitol: diferenças entre revisões

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nova página: {{chembox new | verifiedrevid = 423617535 | Name = Mesquitol | ImageFile = Mesquitol.svg | ImageSize = 250px | ImageName = Chemical structure of mesquitol | IUPACName = 3,4-Dihydro-...
 
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'''Mesquitol''' é um [[flavan-3-ol]], um tipo de flavonoide.<ref>[http://metabolomics.jp/wiki/FL633CNS0001 Mesquitol on metabolomics] - '''metabolomics.jp'''</ref>
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''[[Prosopis juliflora]]'', a [[mesquite]] found in Kenya, shows unusual amount of (-)-mesquitol from its heartwood.<ref>Unusual amount of (-)-mesquitol from the heartwood of Prosopis juliflora. Sirmah Peter, Dumarcay Stephane, Masson Eric and Gerardin Philippe, Natural Product Research, January 2009, Volume 23, Number 2, pages 183-189, {{doi|10.1080/14786410801940968}}</ref>
 
''[[Prosopis juliflora]]'', auma [[mesquite]] foundencontrada inno Kenya[[Quênia]], showsapresenta unusualquantidade amountincomum ofde (-)-mesquitol fromem itsseu heartwoodcerne.<ref>Unusual amount of (-)-mesquitol from the heartwood of Prosopis juliflora. Sirmah Peter, Dumarcay Stephane, Masson Eric and Gerardin Philippe, Natural Product Research, January 2009, Volume 23, Number 2, pages 183-189, {{doi|10.1080/14786410801940968}}</ref>
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Mesquitol with its [[pyrogallol]]-type A-ring is more susceptible to [[quinone]] formation at this ring leading to aryl–aryl bond formation at carbon 5. The structural moieties constitute the [[proteracacinidin]] class of [[proanthocyanidin]]s.<ref>Oligomeric proanthocyanidins: naturally occurring O-heterocycles. Daneel Ferreira and Desmond Slade, Nat. Prod. Rep., 2002, volume 19, pages 517–541, {{doi|10.1039/b008741f}}</ref> [[Mesquitol-(5→8)-catechin]] [[atropisomer]]s can be isolated
from ''[[Prosopis glandulosa]]''.<ref>Synthesis of condensed tannins. Part 17. Oligomeric (2R,3S)-3,3′,4′,7,8-pentahydroxyflavans: atropisomerism and conformation of biphenyl and m-terphenyl analogues from Prosopis glandulosa(‘mesquite’). Esmé Young, Edward V. Brandt, Desmond A. Young, Daneel Ferreira and David G. Roux, J. Chem. Soc., Perkin Trans. 1, 1986, pages 1737-1749, {{doi|10.1039/P19860001737}}</ref>
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[[Categoria:Flavonoides]]
[[Categoria:Fenóis]]